ECOLOGY QUESTION 1993:				L. PETERSON/AP BIOLOGY

	Living organisms play an important role in the recycling of many elements 
	within an ecosystem. Discuss how various types of organisms and their
	biochemical reactions contribute to the recycling or either carbon or
	nitrogen in an ecosystem. Include in your answer one way in which human
	activity has an impact on the nutrient cycle you have chosen.

  
     This question required students to integrate material typically presented at
     widely separated times in their course wor, namely ecology, biochemistry,
     and organismal diversity. Conceptual understanding was extremely important;
     simple recall of words or phrases did not earn points. Students were required
     to choose one cycle, and to trace the pathway(s) of the chosen element through 
     appropriate organisms and metabolic sequences to return to the starting
     material. Description of the carbon cycle involves trophic structure (energy
     transfer) of the ecosystem, and depends heavily on processes of autotrophy 
     (usually photosynthesis) and heterotrophy (usually aerobic respiration).
     The nitrogen cycle is somewhat more complex; and bacteria play key roles.
     Nitrogen compounds play important structural roles in all organisms but are
     less important in energy transfer. Finally, students described an impact of 
     human technology and related this impact ot the chosen cycle.
  
                         NUTRIENT CYCLING
                                (8 POINTS MAXIMUM)
  __  OVERVIEW - Why is recycling necessary?
                            SPECIFIC CYCLE CHOICE
               (GRADE FIRST CYCLE SPECIFICALLY MENTIONED)
  
          CARBON                               NITROGEN
  __  Demonstrates closed C cycle       __  Demonstrates closed N cycle
  __  Carbon sources/pools, locations        __  Nitrogen sources/pools (availability)
  __  Basic process of carbon fixation       __  N2 conversion (N2 -> "usable" form)
         (CO2 -> sugar, biomass or organic form)
  __   Elaboration of autotrophy             __  Elaboration of fixation
  __   Role of respiration (organic C -> CO2)     __  Nitrification (see addendum)
  __  Elaboration of respiration             __  Denitrification (see addendum)
  __  Uniqueness of autotrophy               __  Uniqueness of bacteria to processes
          (universality of respiration)           __  Plant assimilation of N compounds:
                                       inorganic -> organic
  __  Storage forms/products            __  Storage forms/products 
  __  Food chain sequence               __  Food chain sequence
  __  Role of decomposer           __  Role of decomposer
  __  Unusual cases: (see addendum)          __  Unusual cases: (see addendum)
     methanogenesis                deamination
     photorespiration                   ammonification
     chemosynthesis                re-reduction (reductases)
                                   Urea <-> Uric Acid
  
  
  
  
  
  
  
  
  
               HUMAN IMPACT ON CHOSEN CYCLE
                    (3 POINTS MAXIMUM)
  
  __  Identify single human technological impact on cycle
  __  Explanation of impact/consequence
  __  Additional details 
  
                       Nutrient Cycling
                            ADDENDUM
  The intent of this addendum is to clarify details of the scoring standards by providing
  additional technical information, names of organisms, enzymes, etc. which may be
  mentioned by students. It does NOT replace the standards which should be referred to
  for distribution of points, maximum points for certain areas, etc.
  
  CARBON CYCLE
  
  Elaboration of photosynthesis:
    Calvin Cycle biochemistry: complete correct equation
    (RuBP + CO2 -> 2 PGA  or 6 RuBP + 6CO2 + 18 ATP + 12 NADPH2 ->
      6 RuBP + hexose + 18 ADP + 12 NADP, etc.) or mention of enzymes involved
     (ribulose bisphosphate carboxylase/oxygenase or rubisco is most likely) or
     mention that these reactions occur in chloroplasts, in stroma, etc.
     mention of distinction between C3 vs C4-CAM pathways or groups of plants.
     mention of seasonal fluctuations.
  Elaboration of respiration:
     mention of specific steps in respiration where CO2 is released:
     pyruvate -> acetyl-CoA + CO2, Krebs cycle reactions, etc.
     fermentation reactions: pyruvate + NADH -> EtOH + CO2, etc.
  Storage forms/products: standing trees, peat, coal, oil, natural gas, bones, shells, coral,
     chalk, limestone of biogenic origin, etc.
  Unusual or special cases:
     methanogenesis: CO2 + 4 H2 -> CH4 + 2 H2O only bacteria actually do this, but 
     students are more likely to describe the environment in which the bacteria grow,
     such as ruminants (belching cows), swamps (waterlogged, anaerobic soils), etc.
  Photorespiration: in C3 palnts if CO2/O2 ratio is low, RuBP + O2 -> PGA + P-glycolate
     P-glycolyate -> glyoxylate,  glyoxylate + NH2 -> glycine, glycine + NAD -> 
     CO2 + serine + NH3 + NADH
  Chemosynthesis: incorporation of CO2 using an energy source other than light
     (H2, highly reduced organic compounds, etc.)
  
  IMPACT ON CARBON CYCLE:
  Burning fossil fuels -> raises CO2 levels
     may produce greenhouse effect, may stimulate autotrophs
  Clearing/burning forests -> raises CO2 levels or removes autotrophs
     may produce greenhouse effect, may increase CO2 dissolved in oceans, etc.
  Acid rain -> dissolves limestone, releases CO2 or kills autotrophs
     may contribute to greenhouse effect, increase CO2 content of oceans, etc.
  Intensive agriculture/desert irrigation -> increase in autotrophs
     removes CO2 from sources, ties up carbon in storage forms
   
  
  
  
  
  
  
                       Nutrient Cycling
                            ADDENDUM
  
   NITROGEN CYCLE
  
  Elaboration of N2 fixation ("conversion")
     Equation: N2 + 6 H+ + 6e-  -> 2 NH3
     Enzyme complex: nitrogenase or N2ase (strictly anaerobic)
     Specific organisms: Rhizobium, Azotobacter, Klebsiella, Clostridium,
      Nostoc, Anabaena, Gloeotheca, Trichodesmium, etc.
     Distinction between free-living and symbiotic nitrogen-fixing organisms.
     Association of bacteria with plants, legumes, nodulations, leghemoglobin, etc.
  
  Nitrification: in bacteria, NH4+  + 2 O2 -> NO2- + 2 H2O,
                      NO2- + O2 -> NO3-
     this is done by Nitrosomonas, Nitrobacter, etc.
  Denitrification: in bacteria, NO3- -> NO2- -> N2O -> N2
     this is true anaerobic respiration; the nitrogen compound acts as an
     alternative electron acceptor, replacing O2. Pseudomonas can do this,
     also Paracoccus, Bacillus, Thiobacillus, etc. Typically occurs in
     water-logged soils depleted of O2.
  Unusual or special cases:
      Ammonification: usually by bacteria/fungi
          proteins -> amino acids,   amino acids -> NH3
     Re-reduction: many organisms can use NO3 or NO2 but must convert these
     back to NH3 first. This is done by a pair of enzymes, namely nitrate reductase
     and nitrite reductase.
     Some organisms excrete urea and/or uric acid.
     Insectivorous plants (Pitcher Plants, Venus Flytrap, etc.) obtain nitrogenous
     compounds by digesting animals.
  
  IMPACT ON NITROGEN CYCLE:
  Burning fossil fuels -> releases NOx
     contributes to acid rain
  Burning/clearing forest -> increases leaching of N compounds from soil
     decrease in fertility, increased NO3 in runoff water, etc.
  Use of N fertilizers -> kills nitrogen fixers, other soil microbes or ->
  increased NO3 in runoff water.
     decrease in fertility, possible health effects, eutrophication, 
     algal blooms, possible O2 depletion, etc.
  Pesticides -> kill N2 fixers.
     decrease in fertility
  Genetic Engineering of N2ase -> higher plants can fix their own N2?